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CXP5045擴(kuò)鏈劑和相容劑（可以提升低質(zhì)量的回收利用，可在加工過程中使用，以提高聚酯或聚酰胺的熔體強(qiáng)度。HYOSIL CXP 5045還具有高環(huán)氧官能度，這允許與縮合熱塑性塑料快速反應(yīng)，從而導(dǎo)致更高的分子量。）
THYOSIL CXP5045
Chain extender and compatibilizer 擴(kuò)鏈劑和相容劑
Description描述
THYOSIL CXP5045 is a multifunctional polymer specially designed to restore molecular weight and IV (intrinsic viscosity) in degraded polymers.
THYOSIL CXP5045 allows to upgrade low quality recycle and can be used during processing to increase the melt strength of polyesters or polyamide. THYOSIL CXP5045 also has high epoxy functionality, this allows for rapid reaction with condensation thermoplastics, resulting in higher molecular weight.
THYOSIL CXP5045是一種多功能聚合物，專為在分解聚合物中恢復(fù)分子量和IV（特性粘度）而設(shè)計(jì)。
HYOSIL CXP 5045可以提升低質(zhì)量的回收利用，可在加工過程中使用，以提高聚酯或聚酰胺的熔體強(qiáng)度。HYOSIL CXP 5045還具有高環(huán)氧官能度，這允許與縮合熱塑性塑料快速反應(yīng)，從而導(dǎo)致更高的分子量。
Advantages 優(yōu)勢(shì)
ü Higher regrind/recycle yield rate.?更高的回收/回收再生率。
ü Upgrade lower molecular weight polycondensate polymers.?
ü 升級(jí)較低分子量的縮聚物聚合物。
ü Compatibilization of polycondensate alloys.?縮聚物合金的相容性
ü Improved tensile strength.?提高拉伸強(qiáng)度。
ü Enhanced hydrolytic stability.?增強(qiáng)水解穩(wěn)定性。
Typical Properties典型值
These properties are typical, do not constitute specifications
|
Appearance外觀 |
Clear powder清粉狀 |
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Solids (%)固含 |
>99 |
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Tg (oC)玻璃化溫度 |
60 |
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Epoxy equivalent weight (g/mol)環(huán)氧當(dāng)量 |
445 |
Recommended dosage推薦用量
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Plastic塑料 |
Application用于 |
Recommended Dosage推薦用量 (% w/w) |
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Polyesters (PET)聚酯 |
Fiber (staple and filament) 纖維（短纖維和長(zhǎng)絲） |
0.1 to 0.7 |
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Injection/blow molding bottle 注塑/吹塑瓶 |
0.1 to 0.8 |
|
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Sheet, tape and profile extrusion 片材，膠帶和型材擠出 |
0.2 to 1.0 |
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Film and bottle blow molding 薄膜和瓶吹塑 |
0.2 to 1.0 |
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Strapping打包帶 |
0.2 to 1.0 |
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Compatibilization PET/PA-nylon 聚酯與尼龍相容 |
0.4 to 1.5 |
|
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Foam發(fā)泡 |
0.4 to 1.5 |
|
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Polyesters (PETG, PBT, PLA, others) 聚酯（PETG，PBT，PLA，其他） |
Injection Molding注射成型 |
0.1 to 0.3 |
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Fiber纖維 |
0.1 to 0.7 |
|
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Profile extrusion型材擠出 |
0.2 to 1.0 |
|
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Sheet and film片材和薄膜 |
0.2 to 1.0 |
|
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Branching分枝 |
0.5 to 1.5 |
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Foam發(fā)泡 |
0.4 to 1.5 |
|
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Polyamides (nylon, PA 6, other) 聚酰胺（尼龍，PA 6，其他） |
Injection Molding注射成型 |
0.1 to 0.3 |
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Profile extrusion型材擠出 |
0.4 to 1.0 |
|
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Sheet, film and tape 片材，薄膜，膠帶 |
0.4 to 1.5 |
|
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Branching分枝 |
0.5 to 1.5 |
|
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Compatibilization polyester/PA-nylon 增容聚酯/ PA尼龍 |
0.5 to 1.5 |
|
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Polycarbonates (PC) 聚碳酸酯（PC） |
Injection molding注射成型 |
0.1 to 0.3 |
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Hydrolytic stabilization水解穩(wěn)定 |
0.4 to 1.5 |
|
|
Sheet and film片材和薄膜 |
0.4 to 1.5 |
|
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Branching分枝 |
0.5 to 1.5 |
|
|
Other condensation thermoplastics (TPU, POM) 其他冷凝熱塑性塑料（TPU，POM） |
Melt strength熔體強(qiáng)度 |
0.3 to 1.0 |
|
Stabilization穩(wěn)定 |
0.2 to 1.0 |
Processing conditions加工條件
|
Operation操作 |
Procedure步驟 |
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Pre-drying 預(yù)干燥 |
Pre-dry the base plastic at manufacturer’s recommended conditions. 推薦下預(yù)干燥基礎(chǔ)塑料。 |
|
In some instances small amounts of THYOSIL CXP5045 can be compensated for poor or incomplete drying, thus bringing robustness and saving to your operations. 在某些情況下，添加少量的THYOSIL CXP5045可以補(bǔ)償不良或不完全的干燥，從而為您的操作帶來方便和節(jié)省操作。 |
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Hygroscopicity: there is no evidence of bulk absorption of moisture over extended periods of time for THYOSIL CXP5045. At normal conditions of temperature and relative humidity its surface reaches equilibrium saturation through adsorption at less than 0,25% of moisture. At extreme conditions its surface reaches equilibrium saturation at less than 0,50% of moisture. This means that THYOSIL CXP5045 can generally be processed without any drying, even after long exposure to drastic conditions bringing no more than 5ppm moisture per every 0,1% used. 吸濕性：THYOSIL CXP5045在長(zhǎng)時(shí)間內(nèi)沒有大量吸收水分的跡象。在正常的溫度和相對(duì)濕度條件下，其表面通過吸附小于0.25％的水分達(dá)到平衡飽和度。 在極端條件下其表面水分，在小于0.50％達(dá)到平衡飽和。這意味著即使經(jīng)過長(zhǎng)時(shí)間暴露于劇烈的條件下，THYOSIL CXP5045通常也可以進(jìn)行加工處理，每0.1％使用不超過5ppm的水分。 |
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Ins systems where moisture sensitivity is extreme, THYOSIL CXP5045 can be dried in a desiccant dryer ant30°Cfor 1 hour, prior to use. 在潮濕敏感度極高的系統(tǒng)中，THYOSIL CXP5045可以在干燥劑干燥器中于30℃ 干燥1小時(shí)，然后再使用。 |
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Extruder/injection molder temperature profile 擠出機(jī)/注塑機(jī)溫度曲線 |
Where feeding solid THYOSIL CXP5045 in any solid form, except masterbatch, into the first zone of the extruder or infection molder, we recommend to operate this zone at20°Cto40 °Clower temperature than normal. This will prevent early melting and agglomeration of the additive. 在將固體形式除母粒之外的固體THYOSIL CXP5045進(jìn)入擠出機(jī)或感染模塑機(jī)的第一區(qū)域內(nèi)，建議比常溫低 ，在20℃至40℃的溫度下操作該區(qū)域。 這將防止添加劑的早期熔化和附聚。 |
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All other zones should employ normal processing condition as recommended by the plastic’s manufacturer. 所有其他區(qū)域應(yīng)采用塑料制造商推薦的正常加工條件。 |
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Additive thermal stability 添加劑熱穩(wěn)定性 |
THYOSIL CXP5045 is thermally stable up to 320°C. Above this temperature additive decomposition may occur. THYOSIL CXP5045在320°C以下是熱穩(wěn)定的。 高于此溫度可能會(huì)發(fā)生分解。 |
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Residence time 停留時(shí)間 |
THYOSIL CXP5045 reacts quickly. Its reaction will be over 99% complete if at least 3 min residence time is provided at200°Cin a well-mixed system. Alternatively, 45 sec residence time at280°Cwill provide 99% completion. THYOSIL CXP5045快速反應(yīng)。 如果在200℃下在充分混合的系統(tǒng)中至少提供3分鐘的停留時(shí)間，其反應(yīng)將達(dá)到99％以上。 或者，在280℃下停留時(shí)間為45秒將完成99％。 |
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These limits accommodate most extrusion and injection molding processed for the recommended thermoplastics and applications. 這些限制適用于為推薦的熱塑性塑料和應(yīng)用而加工的大多數(shù)擠出和注塑。 |
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For use in polymerization reactors where residence time is over 5 minutes, see recommendations in section “Methods of Dosage”. 用于停留時(shí)間超過5分鐘的聚合反應(yīng)釜中，請(qǐng)參見“劑量方法”一節(jié)中的建議。 |
- THYOSIL CXP5045 should not be processed at temperatures higher than320°C
- THYOSILCXP5045不應(yīng)在高于320°C的加工溫度。
Extruder pressure effects擠出機(jī)壓力效應(yīng)
The use of THYOSIL CXP5045 inreactive extrusion or reactive injection molding operations increases significantly the molecular weight, this lead to an increase in melt viscosity, which in turn raises the pressure observed in the equipment.
The table below exemplifies the large increases in die pressure that are observed in PET as THYOSIL CXP5045 is added to a large extruder. Similar increases are expected in other plastics.
在反應(yīng)性擠出或反應(yīng)性注射成型工具中使用THYOSIL CXP5045顯著增加了分子量，這導(dǎo)致熔體粘度的增加，從而提高了設(shè)備中觀察到的壓力。下表列舉了將THYOSIL CXP5045加入到大型擠出機(jī)中時(shí)在PET中觀察到的模具壓力的大幅增加。 預(yù)計(jì)其他塑料類似增長(zhǎng)。
|
Extrude variable 拉伸變量 |
PET Control控制 |
0,50% THYOSIL CXP5045 |
1,00% THYOSIL CXP5045 |
1,50% THYOSIL CXP5045 |
|
Pressure die壓模 |
1 |
1.25-1.45 |
1.55-1.80 |
1.80-2.00 |
|
Pressure screen 壓力篩 |
1 |
1.25-1.45 |
1.90-1.80 |
1.80-2.00 |
|
Motor power draw 電機(jī)功率 |
1 |
1.05-1.08 |
1.13-1.12 |
1.12-1.15 |
The pressure increases both at the die and in front screen system may be 25% to 100% higher than typical operating pressure for higher usage levels. Instantaneous pressure variations and spikes are due to large instantaneous changes in melt viscosity. At constant temperature, changes in melt viscosity are often due to variable feed rate and/or poor mixing.
在模具和前屏幕系統(tǒng)中的壓力增加可以比用于較高使用水平的典型操作壓力高25％至100％。瞬時(shí)壓力變化和尖峰是由于熔體粘度的瞬間變化很大。 在恒定溫度下，熔體粘度的變化通常是由于可變的進(jìn)料速率和/或混合不良。
The pressure and power draw changes with fluctuations in feed rate are calculated on the table below.
壓力和功率的變化隨著進(jìn)料速度的波動(dòng)而計(jì)算如下表所示。
|
Extrude variable 拉伸變量 |
Steady feed within 5% of target value 穩(wěn)定飼料在目標(biāo)值的5％以內(nèi) |
Steady feed within 10% of target value 穩(wěn)定飼料在目標(biāo)值的10％以內(nèi) |
Steady feed within 20% of target value 穩(wěn)定飼料在目標(biāo)值的20％以內(nèi) |
|
Pressure die壓模 |
± 2.0% |
±4.3% |
±9.0% |
|
Pressure screen 壓力篩 |
±2.5% |
±4.5% |
±9.2% |
|
Pressure draw壓差 |
±0.4% |
±0.8% |
±1.75% |
Troubleshooting故障排除
Ø In case of unexpected high pressure:?如出現(xiàn)意想不到的高壓：
(1)
Decrease the feed rate of THYOSIL CXP5045.降低THYOSIL CXP5045的進(jìn)料速度。
(2)
Decrease the RPM. This decrease pressure on single screw extruders and flood-fed twin-screw extruders, and will decrease hating on starve-fed twin-screw extruders.）
降低轉(zhuǎn)速。 這對(duì)單螺桿擠出機(jī)和擠壓雙螺桿擠出機(jī)的壓力降低，并且將減少對(duì)供給雙螺桿擠出機(jī)的不適
(3)
Slowly increase the temperature, starting from the die and then from the last to the zone.
緩慢升高溫度，從模頭開始，然后從最后到達(dá)區(qū)域。
(4)
With pressure under control, increase the THYOSIL CXP5045 feed slowly.
在控制壓力下，慢慢增加THYOSIL CXP 5045進(jìn)料。
(5)
For steady operation follow recommendations given in the section “extruder pressure effects”
為了穩(wěn)定運(yùn)行，請(qǐng)參閱“擠出機(jī)壓力效應(yīng)”一節(jié)中給出的建議
Safe handling Information
Before using this product, read carefully the Material Safety Data Sheet (MSDS).
Note: The statements above are based on the current state of knowledge. They are intended to describe the product in relation to necessary safety precautions, and should not be used as a warranty of any specific property. Revision: March 2017.
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